Towards Photocatalytic Alkane Oxidation: The Insertion of Dioxygen into a Platinum (II)-Methyl Bond

被引：57

作者：

Taylor, Russell A. ^{[1
]}

Law, David J. ^{[2
]}

Sunley, Glenn J. ^{[2
]}

White, Andrew J. P. ^{[1
]}

Britovsek, George J. P. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 32期

关键词：

alkane oxidation; insertion; photosensitizers; platinum; singlet oxygen; PD-II-HYDROPEROXIDE; C-H ACTIVATION; MOLECULAR-OXYGEN; SINGLET OXYGEN; ALKYL COMPLEXES; PHOTOOXIDATION; HYDRIDE; MECHANISM; FORM; FUNCTIONALIZATION;

D O I：

10.1002/anie.200806187

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Always look on the bright side: The light-driven insertion of dioxygen into a platinum-methyl bond results in a methylperoxo complex (see picture) which decomposes to formaldehyde and a platinum hydroxo complex. This reaction occurs at 1 atm O2 and room temperature within minutes, and proceeds via the formation of singlet oxygen. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5900 / 5903

页数：4

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