A metal-organic framework via the reaction of benzoate with a cationic inorganic material

被引：5

作者：

Swanson, Claudia H. ^{[1
]}

Cummings, Steven P. ^{[1
]}

Grysell, Martin ^{[1
]}

Tran, Dat T. ^{[1
]}

Rogow, David L. ^{[1
]}

Oliver, Allen G. ^{[1
]}

Oliver, Scott R. J. ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

DALTON TRANSACTIONS | 2009年 / 44期

关键词：

CRYSTAL-STRUCTURE; COORDINATION POLYMER; ADSORPTION; HYDROGEN; SITES; COMPLEXES; CATALYSIS;

D O I：

10.1039/b912874c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Our research group previously reported a two-dimensional cationic inorganic material (BING-5, Pb3F5NO3) where nitrate resides in the interlamellar space and can be anion exchanged. Investigation of the possible exchange of nitrate for benzoate led to the discovery of a layered metal-organic framework, lead benzoate hydrate [Pb(C6H5CO2)(2)(OH2)]. The compound crystallizes as colourless plates in the monoclinic space group P2(1)/c. The two dimensional lead-oxygen layers contain bridging benzoate oxygen atoms, with bridging water molecules further supporting the layers. The benzoate molecules are positioned perpendicular to the layers and form a hydrophobic bilayer region. The material shows basic character when immersed in various solvents suggesting potential as a base catalyst.

引用

页码：9849 / 9853

页数：5

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