C-H activation by Cu(III)2O2 intermediate with secondary amino ligand

被引：18

作者：

Arii, H

Saito, Y

Nagatomo, S

Kitagawa, T

Funahashi, Y

Jitsukawa, K

Masuda, H ^{[1
]}

机构：

[1] Nagoya Inst Technol, Dept Appl Chem, Showa Ku, Nagoya, Aichi 4668555, Japan

[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 02期

关键词：

D O I：

10.1246/cl.2003.156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Cu(I) complex having a newly designed tridentate ligand i-Bu3CY with dioxygen has given an active bis(mu-oxo)dicopper(III) complex, which has exhibited a unique intramolecular hydroxylation of the beta-methine carbon of isobutyl group of the ligand.

引用

页码：156 / 157

页数：2

共 19 条

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