Design and preparation of organic-inorganic hybrid catalysts

被引:1189
作者
Wight, AP [1 ]
Davis, ME [1 ]
机构
[1] CALTECH, Pasadena, CA 91125 USA
关键词
D O I
10.1021/cr010334m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The design and preparation of organic-inorganic hybrid catalysts was studied. The organic functionality was covalently attached to porous inorganic solids. The covalently attached organic groups were sufficiently stable for recycling and reuse and was easily modified to create a variety of catalytic sites. The spatial distribution of the functional groups was examined by various methods including the adsorption of probe molecules.
引用
收藏
页码:3589 / 3613
页数:25
相关论文
共 115 条
[1]   Best design of heterogenized β-aminoalcohols for improvement of enantioselective addition of diethylzinc to benzaldehyde [J].
Abramson, S ;
Laspéras, M ;
Galarneau, A ;
Desplantier-Giscard, D ;
Brunel, D .
CHEMICAL COMMUNICATIONS, 2000, (18) :1773-1774
[2]   Heterogeneous enantioselective carbon-carbon bond formation:: role of the inorganic support in the synthesis and activity of supported chiral auxiliaries [J].
Abramson, S ;
Bellocq, N ;
Laspéras, M .
TOPICS IN CATALYSIS, 2000, 13 (03) :339-345
[3]   AMINO-GROUPS IMMOBILIZED ON SILICA-GEL - AN EFFICIENT AND REUSABLE HETEROGENEOUS CATALYST FOR THE KNOEVENAGEL CONDENSATION [J].
ANGELETTI, E ;
CANEPA, C ;
MARTINETTI, G ;
VENTURELLO, P .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (01) :105-107
[4]   SILICA-GEL FUNCTIONALIZED WITH AMINO-GROUPS AS A NEW CATALYST FOR KNOEVENAGEL CONDENSATION UNDER HETEROGENEOUS CATALYSIS CONDITIONS [J].
ANGELETTI, E ;
CANEPA, C ;
MARTINETTI, G ;
VENTURELLO, P .
TETRAHEDRON LETTERS, 1988, 29 (18) :2261-2264
[5]   Periodic mesoporous organosilicas with organic groups inside the channel walls [J].
Asefa, T ;
MacLachlan, MJ ;
Coombs, N ;
Ozin, GA .
NATURE, 1999, 402 (6764) :867-871
[6]  
Asefa T, 2000, ANGEW CHEM INT EDIT, V39, P1808, DOI 10.1002/(SICI)1521-3773(20000515)39:10<1808::AID-ANIE1808>3.0.CO
[7]  
2-G
[8]   TEMPLATING OF MESOPOROUS MOLECULAR-SIEVES BY NONIONIC POLYETHYLENE OXIDE SURFACTANTS [J].
BAGSHAW, SA ;
PROUZET, E ;
PINNAVAIA, TJ .
SCIENCE, 1995, 269 (5228) :1242-1244
[9]   Amberlyst A-27, an efficient heterogeneous catalyst for the Michael reaction of nitroalkanes with beta-substituted alkene acceptors [J].
Ballini, R ;
Marziali, P ;
Mozzicafreddo, A .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (09) :3209-3211
[10]   Synthesis of a large pore phenyl-modified mesoporous silica and its characterization by nitrogen and benzene sorption? [J].
Bambrough, CM ;
Slade, RCT ;
Williams, RT .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (03) :569-571