Gas-phase enzyme catalysis using immobilized lipase for ester production

被引:10
作者
Barton, JW [1 ]
Reed, EK [1 ]
Davison, BH [1 ]
机构
[1] OAK RIDGE NATL LAB,DIV CHEM TECHNOL,OAK RIDGE,TN 37831
关键词
D O I
10.1023/A:1018448502602
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Bench-scale reactors were operated in continuous recycle and single-pass modes using immobilized porcine lipase to catalyze gas-phase esterification of ethyl alcohol with two carboxylic acids (acetic acid and propionic acid). Approximately one order of magnitude increases (over uncatalyzed reactions) in conversion were achieved; production concentrations ranged from 0.1 to 0.5 mM in air, and were affected strongly by substrate concentration and acid-induced enzyme inactivation.
引用
收藏
页码:747 / 750
页数:4
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