Carbon-heteroatom bond-forming reactions mediated by cerium(IV) ammonium nitrate: An overview

被引：107

作者：

Nair, V ^{[1
]}

Panicker, SB ^{[1
]}

Nair, LG ^{[1
]}

George, TG ^{[1
]}

Augustine, A ^{[1
]}

机构：

[1] CSIR, Reg Res Lab, Div Organ Chem, Trivandrum 695019, Kerala, India

来源：

SYNLETT | 2003年 / 02期

关键词：

cerium(IV) ammonium nitrate; radical reactions; bond-forming reactions; heteroatoms; oxidations;

D O I：

10.1055/s-2003-36775

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

As a powerful one-electron oxidant, cerium(IV) ammonium nitrate (CAN) is useful for a variety of oxidative transformations including carbon-carbon bond formation. Recent work has also demonstrated the usefulness of CAN in carbon-heteroatom bond-forming reactions. Particularly noteworthy is the effectiveness of CAN in building C-N, C-S, C-Se. C-Br, and C-I bonds. This account is aimed at creating awareness among organic chemists about such reactions with potential application in the synthesis of a variety of building blocks.

引用

页码：156 / 165

页数：10

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