Excess molar enthalpies of propyl propanoate plus hexane plus benzene at 298.15 K and 308.15 K

被引:20
作者
Casas, H
Segade, L
Franjo, C
Jiménez, E [1 ]
Andrade, MIP
机构
[1] Univ A Coruna, Fac Ciencias, Dept Fis, Coruna 15071, Spain
[2] Univ Santiago de Compostela, Fac Fis, Dept Fis Aplicada, Santiago De Compostela 15706, Spain
关键词
D O I
10.1021/je990265x
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar enthalpies of the ternary system {x(1) propyl propanoate + x(2) hexane + (1 - x(1) - x(2)) benzene} and of their binary mixtures {x(1) propyl propanoate + x(2) hexane}, {x(1) propyl propanoate + x(2) benzene}, and {x(1) hexane + x(2) benzene} have been determined at 298.15 K and 308.15 K and atmospheric pressure, over the whole composition range. The excess molar enthalpies were measured using a Calvet microcalorimeter. The experimental values were compared with the results obtained with empirical expressions for estimating ternary properties from binary data.
引用
收藏
页码:445 / 449
页数:5
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