Optical properties of colloidal PbSe nanocrystals

被引:437
作者
Du, H
Chen, CL
Krishnan, R
Krauss, TD [1 ]
Harbold, JM
Wise, FW
Thomas, MG
Silcox, J
机构
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
[2] Univ Rochester, Dept Elect & Comp Engn, Rochester, NY 14627 USA
[3] Cornell Univ, Dept Appl Phys, Ithaca, NY 14853 USA
关键词
D O I
10.1021/nl025785g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present the structural and optical characterization of colloidal PbSe nanocrystals. The lowest-energy exciton transitions in these structures, with diameters between 3 and 8 nm, occur at wavelengths between 1.0 and 1.85 mum. Band-edge luminescence spectra with quantum yields as high as 80% are observed. Unexpectedly long (similar to300 ns) luminescence lifetimes are observed. These properties are promising for applications in optoelectronics and microscopy.
引用
收藏
页码:1321 / 1324
页数:4
相关论文
共 29 条
[1]   Anisotropy-induced optical transitions in PbSe and PbS spherical quantum dots [J].
Andreev, AD ;
Lipovskii, AA .
PHYSICAL REVIEW B, 1999, 59 (23) :15402-15404
[2]   Identification of atomic-like electronic states in indium arsenide nanocrystal quantum dots [J].
Banin, U ;
Cao, YW ;
Katz, D ;
Millo, O .
NATURE, 1999, 400 (6744) :542-544
[3]   ABSORPTION AND FLUORESCENCE PROPERTIES OF CYANINE DYES [J].
BENSON, RC ;
KUES, HA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1977, 22 (04) :379-383
[4]   QUANTUM CONFINEMENT OF PBS MICROCRYSTALS IN GLASS [J].
BORRELLI, NF ;
SMITH, DW .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 180 (01) :25-31
[5]   Semiconductor nanocrystals as fluorescent biological labels [J].
Bruchez, M ;
Moronne, M ;
Gin, P ;
Weiss, S ;
Alivisatos, AP .
SCIENCE, 1998, 281 (5385) :2013-2016
[6]   Quantum dot bioconjugates for ultrasensitive nonisotopic detection [J].
Chan, WCW ;
Nie, SM .
SCIENCE, 1998, 281 (5385) :2016-2018
[7]   (CdSe)ZnS core-shell quantum dots: Synthesis and characterization of a size series of highly luminescent nanocrystallites [J].
Dabbousi, BO ;
RodriguezViejo, J ;
Mikulec, FV ;
Heine, JR ;
Mattoussi, H ;
Ober, R ;
Jensen, KF ;
Bawendi, MG .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (46) :9463-9475
[8]  
EFROS AL, 1982, SOV PHYS SEMICOND+, V16, P772
[9]   Synthesis and characterization of strongly luminescing ZnS-Capped CdSe nanocrystals [J].
Hines, MA ;
Guyot-Sionnest, P .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (02) :468-471
[10]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427