Fully reversible guest exchange in tetraphosphonate cavitand complexes probed by fluorescence spectroscopy

被引:57
作者
Biavardi, Elisa [2 ,3 ]
Battistini, Gionata [1 ]
Montalti, Marco [1 ]
Yebeutchou, Roger M. [2 ,3 ]
Prodi, Luca [1 ]
Dalcanale, Enrico [2 ,3 ]
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, Latemar Unit, I-40126 Bologna, Italy
[2] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy
[3] INSTM UdR Parma, I-43100 Parma, Italy
关键词
D O I
10.1039/b801729h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report here the monitoring of reversible guest inclusion in phosphonate cavitands through a large increase in luminescence intensity caused by the modulation of the exoergonicity of an electron-transfer reaction.
引用
收藏
页码:1638 / 1640
页数:3
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