Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(V) compound

被引:23
作者
Koposov, AY [1 ]
Nemykin, VN [1 ]
Zhdankin, VV [1 ]
机构
[1] Univ Minnesota, Dept Chem, Duluth, MN 55812 USA
关键词
D O I
10.1039/b506573a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single crystal X-ray structures of two 2-iodylbenzenesulfonamides reveal a combination of intra- and intermolecular I center dot center dot center dot O interactions leading to a typical hexacoordinated and a unique heptacoordinated iodine(V) center.
引用
收藏
页码:998 / 1000
页数:3
相关论文
共 36 条
[1]   SECONDARY BONDING .6. DISTORTED OCTAHEDRAL GEOMETRY IN SELENINYL DICHLORIDE-DIOXAN (1-1) AND IODYLBENZENE [J].
ALCOCK, NW ;
SAWYER, JF .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (01) :115-120
[2]  
Allen F. H., 1987, J CHEM SOC P2, pS1
[3]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[4]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[5]  
[Anonymous], 1996, CAMERON
[6]   CRYSTALS version 12: software for guided crystal structure analysis [J].
Betteridge, PW ;
Carruthers, JR ;
Cooper, RI ;
Prout, K ;
Watkin, DJ .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :1487-1487
[7]   Synthesis, characterization, and computational study of the trans-IO2F52- anion [J].
Boatz, JA ;
Christe, KO ;
Dixon, DA ;
Fir, BA ;
Gerken, M ;
Gnann, RZ ;
Mercier, HPA ;
Schrobilgen, GJ .
INORGANIC CHEMISTRY, 2003, 42 (17) :5282-5292
[8]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[9]   ON THE PROBLEM OF HEPTACOORDINATION - VIBRATIONAL-SPECTRA, STRUCTURE, AND FLUXIONALITY OF IODINE HEPTAFLUORIDE [J].
CHRISTE, KO ;
CURTIS, EC ;
DIXON, DA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (04) :1520-1526
[10]  
GOUGOUTAS JZ, 1981, CRYST STRUCT COMMUN, V10, P489