A highly reactive functional model for catechol 1,2-dioxygenase: Reactivity studies of iron(III) catecholate complexes of bis[(2-pyridyl)methyl][(1-methylimidazol-2-yl)methyl]amine

被引:58
作者
Duda, M [1 ]
Pascaly, M [1 ]
Krebs, B [1 ]
机构
[1] UNIV MUNSTER,INST ANORGAN CHEM,D-48149 MUNSTER,GERMANY
关键词
D O I
10.1039/a700614d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The system consisting of an iron(III) salt and bis[(2-pyridyl)methyl] [(1-methylimidazol-2-yl)methyl]amine (bpia) in methanol reacts with various catechols with insertion of dioxygen; in the case of 3,5-di-tert-butylcatechol the efficient catalytic activity of the system is shown.
引用
收藏
页码:835 / 836
页数:2
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