Inclusion by a diol host compound: structure and dynamics of volatile guest exchange

被引：28

作者：

Caira, MR ^{[1
]}

Nassimbeni, LR

Toda, F

Vujovic, D

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

[2] Okayama Univ Sci, Fac Sci, Dept Chem, Okayama 7000005, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2001年 / 11期

关键词：

D O I：

10.1039/b105248a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,1,6,6-Tetraphenylhexa-2,4-diyne-1,6-diol (H) forms inclusion compounds with furan (1 and 2). tetrahydrofuran (3) and thiophene (4). 1, H . (FUR)-F-1/2 (H : G = 1:1/2), is a true clathrate, with the furan guest located in a cage formed by the host. The remaining structures (H:G = 1:2) 2, H . 2FUR, 3, H . 2THF and 4, H . 2THIO are isostructural with guests located in channels. Selectivity and guest exchange reactions have been analysed and correlated to the topologies of the inclusion compounds.

引用

页码：2119 / 2124

页数：6

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