Enantioselective catalysis - Part 124. Enantioselective Michael reaction catalyzed by optically active transition metal complexes

被引：21

作者：

Brunner, H ^{[1
]}

Krumey, C ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 142卷 / 01期

关键词：

Michael reaction; enantioselective catalysis; transition metal complexes;

D O I：

10.1016/S1381-1169(98)00283-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Michael reaction of acrolein 2 with ethyl 2-oxocyclohexanecarboxylate 1 can be catalyzed enantioselectively with a number of optically active transition metal complexes or in situ combinations of transition metal compounds and optically active ligands. The best results up to 47% ee could be obtained with Co(acac)(2) and 1,2-diphenylethylenediamine. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：7 / 15

页数：9

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