Two-Dimensional Crystal Engineering: A Four-Component Architecture at a Liquid-Solid Interface

被引：143

作者：

Adisoejoso, Jinne ^{[2
,3
]}

Tahara, Kazukuni ^{[1
]}

Okuhata, Satoshi ^{[1
]}

Lei, Shengbin ^{[2
,3
]}

Tobe, Yoshito ^{[1
]}

De Feyter, Steven ^{[2
,3
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Div Frontier Mat Sci, Osaka 5608531, Japan

[2] Katholieke Univ Leuven, INPAC, B-3001 Louvain, Belgium

[3] Katholieke Univ Leuven, Dept Chem, Div Mol & Nanomat, B-3001 Louvain, Belgium

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 40期

关键词：

host-guest systems; interfaces; porosity; scanning tunneling microscopy; self-assembly; MOLECULAR NETWORKS; ORGANIC ALLOYS; POROUS NETWORK; SURFACE; TEMPLATE; KAGOME; 3-COMPONENT; ACID; PHTHALOCYANINE; MANIPULATION;

D O I：

10.1002/anie.200900436

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Get it together: A four-component 2D crystal has been formed at a liquid-solid interface and successfully visualized by scanning tunneling microscopy. Simply premixing the four components and applying the solution onto the graphite surface leads to the spontaneous self-assembly of the 2D crystal. Selected guest molecules induce a structural transformation of the host network from nonporous to porous by coadsorption inside the formed pores. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7353 / 7357

页数：5

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