Solvent-vapor treatment induced performance enhancement of poly(3-hexylthiophene):methanofullerene bulk-heterojunction photovoltaic cells

被引：282

作者：

Zhao, Yun ^{[1
]}

Xie, Zhiyuan ^{[1
]}

Qu, Yao ^{[1
]}

Geng, Yanhou ^{[1
]}

Wang, Lixiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Grad Sch, Changchun 130022, Peoples R China

来源：

APPLIED PHYSICS LETTERS | 2007年 / 90卷 / 04期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1063/1.2434173

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The authors report enhanced poly(3-hexylthiophene) (P3HT):methanofullerene (PCBM) bulk-heterojunction photovoltaic cells via 1,2-dichlorobenzene (DCB) vapor treatment and thermal annealing. DCB vapor treatment can induce P3HT self-organizing into ordered structure leading to enhanced absorption and high hole mobility. Further annealing the device at a high temperature, PCBM molecules begin to diffuse into aggregates and together with the ordered P3HT phase form bicontinuous pathways in the entire layer for efficient charge separation and transport. Compared to the control device that is merely annealed, optical absorption, short-circuit current, and power conversion efficiency are increased for the DCB vapor-treated cell. (c) 2007 American Institute of Physics.

引用

页数：3

共 14 条

[1] Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO
[2] 2-A
[3] Influence of nanomorphology on the photovoltaic action of polymer-fullerene composites
Chirvase, D
Parisi, J
Hummelen, JC
Dyakonov, V
[J]. NANOTECHNOLOGY, 2004, 15 (09) : 1317 - 1323
[4] Conjugated polymer photovoltaic cells
Coakley, KM
McGehee, MD
[J]. CHEMISTRY OF MATERIALS, 2004, 16 (23) : 4533 - 4542
[5] Correlation between structural and optical properties of composite polymer/fullerene films for organic solar cells
Erb, T
Zhokhavets, U
Gobsch, G
Raleva, S
Stühn, B
Schilinsky, P
Waldauf, C
Brabec, CJ
[J]. ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (07) : 1193 - 1196
[6] Device annealing effect in organic solar cells with blends of regioregular poly(3-hexylthiophene) and soluble fullerene
Kim, Y
Choulis, SA
Nelson, J
Bradley, DDC
Cook, S
Durrant, JR
[J]. APPLIED PHYSICS LETTERS, 2005, 86 (06) : 1 - 3
[7] High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends
Li, G
Shrotriya, V
Huang, JS
Yao, Y
Moriarty, T
Emery, K
Yang, Y
[J]. NATURE MATERIALS, 2005, 4 (11) : 864 - 868
[8] Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology
Ma, WL
Yang, CY
Gong, X
Lee, K
Heeger, AJ
[J]. ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) : 1617 - 1622
[9] Hole transport in poly(phenylene vinylene)/methanofullerene bulk-heterojunction solar cells
Melzer, C
Koop, EJ
Mihailetchi, VD
Blom, PWM
[J]. ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (09) : 865 - 870
[10] Space-charge limited photocurrent
Mihailetchi, VD
Wildeman, J
Blom, PWM
[J]. PHYSICAL REVIEW LETTERS, 2005, 94 (12)

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