Cyclisation of dienes using phosphorus-centred radicals to form organophosphorus adducts

被引：65

作者：

Jessop, CM

Parsons, AF ^{[1
]}

Routledge, A

Irvine, D

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Uniqema, Middlesbrough TS90 9JE, Cleveland, England

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 03期

基金：

英国生物技术与生命科学研究理事会;

关键词：

cyclisation; dienes; phosphorus compounds; radicals and radical reactions;

D O I：

10.1016/S0040-4039(02)02610-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of various dienes with phosphites or related phosphorus hydrides, under free radical cyclisation conditions, affords cyclic organophosphorus adducts. This quick, mild and technically clean approach affords 5- and 6-ring carbocycles and heterocycles in good to excellent yield. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：479 / 483

页数：5

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[3]

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