Substitution effect of Zn and Cu in MgB2 on Tc and structure

被引:75
作者
Kazakov, SM
Angst, M
Karpinski, J [1 ]
Fita, IM
Puzniak, R
机构
[1] Swiss Fed Inst Technol, Solid State Phys Lab, CH-8093 Zurich, Switzerland
[2] Polish Acad Sci, Inst Phys, Warsaw, Poland
关键词
MgB2; superconductors; lattice constants; transition temperature;
D O I
10.1016/S0038-1098(01)00207-1
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The investigation of Zn substitution in MgB2 polycrystalline samples shows that about 0.1 Zn can be substituted in the structure of Mg deficient samples while it can not be substituted in stoichiometric MgB2. As a result of the isovalent Zn substitution into the Mg position of Mg deficient samples the a and c lattice constants increase by about 0.17% and 0.2% respectively. Susceptibility measurements show a slight lowering of T,by about 0.5 K for 0.05 Zn, which decreases to 0.2 K for 0.1 Zn substitution. Investigation of the pressure derivative of T-c shows dT(c)/dp = -0.15 K/kbar independent of Zn content. Substitution of Cu leads to multiphase samples without any changes of lattice constants, which indicates that Cu does not enter the structure of MgB2. The Cu substitution broadens the superconducting transition considerably, while the onset remains unchanged. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1 / 5
页数:5
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