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Kinetic and electron spin resonance analysis of RAFT polymerization of styrene

被引：68
作者：
Calitz, FM
Tonge, MP
Sanderson, RD
机构：
[1] Univ Stellenbosch, Dept Chem, Div Polymer Sci, UNESCO Ctr Macromol & Mat, ZA-7602 Matieland, South Africa
[2] Univ Sydney, Sch Chem, Key Ctr Polymer Colloids, Sydney, NSW 2006, Australia
来源：
MACROMOLECULES | 2003年 / 36卷 / 01期
关键词：
D O I：
10.1021/ma025607+
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetic and electron spin resonance analysis of reversible addition-fragmentation chain-transfer (RAFT) polymerization of styrene was discussed. It was found that the time dependence of the intermediate radical concentration varies significantly with the type of RAFT agent. It was also found that the RAFT process is not particularly sensitive to oxygen.
引用
收藏
页码：5 / 8
页数：4
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