Ligand- and anion-controlled formation of silver alkynyl oligomers from soluble precursors

被引：41

作者：

Chen, Mei-Li ^{[1
]}

Xu, Xue-Fei ^{[1
]}

Cao, Ze-Xing ^{[1
]}

Wang, Quan-Ming ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 06期

关键词：

D O I：

10.1021/ic702023e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel silver(I) alkynyl cluster complexes ([Ag-5(bpy)(4)(C CBut)(2)](3+), [Ag-8(bpy)(6)(C CBut)(4)](4+), and [Ag-12(bpy)(4)(C=-CBut)(6)(CF3CO2)6]) have been synthesized by reacting soluble polymeric precursors with bipyridine ligands, and control of the nuclearity can be achieved by varying the molar ratio of the reactants and using different types of anions.

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页码：1877 / 1879

页数：3

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