Ring-opening of lactides and related cyclic monomers by triaryltin(IV) alkoxides and amides

被引：24

作者：

Chisholm, MH ^{[1
]}

Delbridge, EE ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 14期

关键词：

D O I：

10.1039/b102896k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ar3SnX, where Ar = p-MeC6H4, p-CF3C6H4 or Ph and X = OBut or NMe2, are catalyst precursors for the ring-opening of lactides in benzene at 80 degreesC and the rate of ring-opening of lactides and a variety of related cyclic monomers is influenced by Ar and X such the chemistry of the ring-opening event and the initially formed product may be examined.

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页码：1308 / 1309

页数：2

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