New preparative procedure for the synthesis of chloroalkyl sulfides

被引：8

作者：

Russavskaya, NV ^{[1
]}

Korchevin, NA ^{[1
]}

Alekminskaya, OV ^{[1
]}

Sukhomazova, EN ^{[1
]}

Levanova, EP ^{[1
]}

Deryagina, EN ^{[1
]}

机构：

[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Div, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

Sulfur; Sulfide; Organic Chemistry; Polymethylene; Chlorine;

D O I：

10.1023/A:1022540002086

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of thiols with dihaloalkanes in the system hydrazine hydrate-base leads to alkyl(chloroalkyl) sulfides with different positions of the chlorine atom with respect to sulfur. The developed one-step procedure for the synthesis of such unsymmetrical sulfides is most suitable for arenethiols and alkanethiols having a long polymethylene chain. The reaction mechanism is discussed.

引用

页码：1445 / 1448

页数：4

共 10 条

[1] Reactions of diorganyl disulfides with dihaloalkanes in basic reductive media. Synthesis of bis(organylthio)alkanes [J].

Alekminskaya, OV ;

Russavskaya, NV ;

Korchevin, NA ;

Deryagina, EN .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2002, 72 (01) :75-78

[2]

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[3]

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[4]

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[5]

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[6]

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[7]

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[8]

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[9]

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[10]

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