New fluorescent probes for monitoring polymerisation reactions -: 1.: Synthesis, solvatochromism and emission properties

被引：28

作者：

Bosch, P

Fernández-Arizpe, A

Mateo, JL

Lozano, AE

Noheda, P

机构：

[1] CSIC, Inst Polimeros, Madrid, Spain

[2] CSIC, Inst Quim Organ, E-28006 Madrid, Spain

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2000年 / 133卷 / 1-2期

关键词：

fluorescent probes; solvatochromism; dipolar moments; polymerisation;

D O I：

10.1016/S1010-6030(00)00226-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of three new highly fluorescent compounds is reported and the basic spectroscopic properties of them described, discussed and compared with those of some structurally related fluorescent compounds usually used as fluorescent probes. The effect of the solvent on ambient temperature absorption and fluorescence spectra, and the solvatochromic properties observed for both ground and first excited states of all the probes were used to evaluate their first excited dipole moments using the solvatochromic shift method (Bakhshiev's correlation). (C) 2000 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：51 / 57

页数：7

相关论文

共 33 条

[1] HYDROGEN-BONDING .8. POSSIBLE EQUIVALENCE OF SOLUTE AND SOLVENT SCALES OF HYDROGEN-BOND BASICITY OF NON-ASSOCIATED COMPOUNDS [J].

ABRAHAM, MH ;

BUIST, GJ ;

GRELLIER, PL ;

MCGILL, RA ;

PRIOR, D ;

OLIVER, S ;

TURNER, E ;

MORRIS, JJ ;

TAYLOR, PJ ;

NICOLET, P ;

MARIA, PC ;

GAL, JF ;

ABBOUD, JLM ;

DOHERTY, RM ;

KAMLET, MJ ;

SHUELY, WJ ;

TAFT, RW .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1989, 2 (07) :540-552

[2] BEHAVIOR AND CONTROL OF NUTRIENTS IN THE ENHANCED AEROBIC DIGESTION PROCESS - PILOT-SCALE STUDIES [J].

ANDERSON, BC ;

MAVINIC, DS .

ENVIRONMENTAL TECHNOLOGY, 1993, 14 (04) :301-318

[3]

BAKHSHIEV NG, 1964, OPT SPEKTROSK+, V16, P821

[4] CONSIDERATIONS ON THE DIPOLE-MOMENT OF MOLECULES FORMING THE TWISTED INTRAMOLECULAR CHARGE-TRANSFER STATE [J].

BAUMANN, W ;

BISCHOF, H ;

FROHLING, JC ;

BRITTINGER, C ;

RETTIG, W ;

ROTKIEWICZ, K .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1992, 64 (01) :49-72

[5] Detection of hydrophobic microdomains in aqueous solutions of amphiphilic polymers using fluorescent molecular rotors [J].

Benjelloun, A ;

Brembilla, A ;

Lochon, P ;

Adibnejad, M ;

Viriot, ML ;

Carre, MC .

POLYMER, 1996, 37 (05) :879-883

[6]

*BIOSYM MSI, 1996, CER 2 VERS 2 0 MOL M

[7] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[8] 1,1-dicyano-2-[6-(dimethylamino)naphthalen-2-yl]propene (DDNP): A solvent polarity and viscosity sensitive fluorophore for fluorescence microscopy [J].

Jacobson, A ;

Petric, A ;

Hogenkamp, D ;

Sinur, A ;

Barrio, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (24) :5572-5579

[9] SOLVATOCHROMIC COMPARISON METHOD .6. PI-STAR SCALE OF SOLVENT POLARITIES [J].

KAMLET, MJ ;

ABBOUD, JL ;

TAFT, RW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) :6027-6038

[10] INTRAMOLECULAR CHARGE-TRANSFER PROPERTIES OF DICYANOVINYL-SUBSTITUTED AROMATICS [J].

KATRITZKY, AR ;

ZHU, DW ;

SCHANZE, KS .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (15) :5737-5742

← 1 2 3 4 →