Nonionic surfactant properties of methoxypolyoxyethylene dodecanoate compared with polyoxyethylene dodecylether

被引:19
作者
Hama, I
Sakaki, M
Sasamoto, H
机构
[1] Lion Corp., Tokyo
[2] Lion Corporation, Process Development Research Center, Edogawa-ku, Tokyo 132
关键词
alcohol ethoxylate; broad ethylene oxide adduct distribution; ethoxylated fatty methyl ester; ethylene oxide; foam breaking; foaming; gelling region; narrow ethylene oxide adduct distribution; phase diagram; wettability;
D O I
10.1007/s11746-997-0226-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Nonionic surfactant properties of methoxypolyoxyethylene dodecanoate [C-12-EFME; C11H23CO(OCH2CH2)(n)CH3] with varying ethylene oxide (EO) adduct distributions were compared with those of polyoxyethylene dodecylether [C-12-alcohol ethoxylate (AE); C12H25O(CH2CH2O)(n)H]. The gelling region of C-12-EFME was much smaller than that of C-12-AE due to the effects of the ester bond and the terminal methyl group. When the EO adduct distribution of EFME is narrowed, the cloud point and the ability to lower interfacial tension do not change appreciably. Other effects of narrow distribution on EFME performance include a decrease in the gellation region and better foam breaking and wetting.
引用
收藏
页码:829 / 835
页数:7
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