Synthesis and characterisation of tetrathiafulvalenyl- and ferrocenyl-triphenylenes

被引：27

作者：

Cooke, G

Radhi, A

Boden, N

Bushby, RJ

Lu, ZB

Brown, S

Heath, SL

机构：

[1] Northumbria Univ, Sch Appl & Mol Sci, Newcastle Upon Tyne NE1 8ST, Tyne & Wear, England

[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[3] Univ Leeds, SOMS Ctr, Leeds LS2 9JT, W Yorkshire, England

[4] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

TETRAHEDRON | 2000年 / 56卷 / 21期

基金：

英国工程与自然科学研究理事会;

关键词：

tetrathiafulvalene; ferrocenes; triphenylene; electrochemistry; molecular modelling;

D O I：

10.1016/S0040-4020(00)00250-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis, electrochemistry and mesogenic properties of novel tetrathiafulvalenyl- and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivatives displaying a discotic mesophase. Solution electrochemistry of derivatives 7 and 13 has revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3385 / 3390

页数：6

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