Preparation and characterization of polyacrylic acid-poly(vinyl alcohol)-based interpenetrating hydrogels

被引：21

作者：

Hernandez, Rebeca ^{[1
]}

Lopez, Daniel ^{[1
]}

Mijangos, Carmen ^{[1
]}

机构：

[1] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2006年 / 102卷 / 06期

关键词：

polyacrylic acid hydrogels; viscoelastic properties; swelling properties; interpenetrating polymer hydrogels;

D O I：

10.1002/app.24397

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Some structural features of hydrogels from poly(acrylic acid) (PAAc) of various crosslinking degrees have been investigated through mechanical and swelling measurements. Interpenetrating polymer hydrogels (IPHs) of poly(vinyl alcohol) (PVA) and PAAc have been prepared by a sequential method: crosslinked PAAc chains were formed in aqueous solution by crosslinking copolymerization of acrylic acid and N,N-methylenebisacrylamide in the presence of PVA. The application of freeze-thaw (F-T) cycles leads to the formation of a PVA hydrogel within the synthesized PAAc hydrogel. The swelling and viscoelastic properties of the IPHs were evaluated as a function of the content of crosslinker and the application of one F-T cycle. (c) 2006 Wiley Periodicals, Inc.

引用

页码：5789 / 5794

页数：6

共 26 条

[1]

[Anonymous], 2011, J MATER CHEM, DOI DOI 10.1039/c1jm10277j

[2]

BANDRUP J., 1989, POLYM HDB

[3]

Bell CL, 1995, ADV POLYM SCI, V122, P125

[4] Polysiloxanes in macromolecular architecture [J].

Bischoff, R ;

Cray, SE .

PROGRESS IN POLYMER SCIENCE, 1999, 24 (02) :185-219

[5]

Byun JG, 1996, J APPL POLYM SCI, V61, P697, DOI 10.1002/(SICI)1097-4628(19960725)61:4<697::AID-APP13>3.0.CO

[6]

2-V

[7] Inhomogeneities in poly(acryrlamide) gels: position-dependent elastic modulus measurements [J].

Durmaz, S ;

Okay, O .

POLYMER BULLETIN, 2001, 46 (05) :409-418

[8]

DUSEK K, 1982, DEV POLYM, V3, P143

[9] PH-SENSITIVE MEMBRANES FROM POLY(VINYL ALCOHOL) POLY(ACRYLIC ACID) INTERPENETRATING NETWORKS [J].

GUDEMAN, LF ;

PEPPAS, NA .

JOURNAL OF MEMBRANE SCIENCE, 1995, 107 (03) :239-248

[10] PREPARATION AND CHARACTERIZATION OF PH-SENSITIVE, INTERPENETRATING NETWORKS OF POLY(VINYL ALCOHOL) AND POLY(ACRYLIC ACID) [J].

GUDEMAN, LF ;

PEPPAS, NA .

JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 55 (06) :919-928

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