A stereoselective total synthesis of (-)-rishitin

被引：17

作者：

Chen, J ^{[1
]}

Marx, JN ^{[1
]}

机构：

[1] TEXAS TECH UNIV,DEPT CHEM & BIOCHEM,LUBBOCK,TX 79409

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(97)00228-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthesis of(-)-rishitin (1) is reported, starting with chiral pool molecules. The crucial step is a stereoselective vinyl radical cyclization, which gives a 10:1 ratio of 21 to 22. (C) 1997 Elsevier Science Ltd.

引用

页码：1889 / 1892

页数：4

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