Helium gas pressure cell for pressures up to 1 kbar (0.1 GPa) in conjunction with the cold head of a closed-cycle He refrigerator

被引:18
作者
Jeftic, J
Kindler, U
Spiering, H
Hauser, A
机构
[1] UNIV MAINZ, INST ANORGAN CHEM & ANALYT CHEM, D-55099 MAINZ, GERMANY
[2] UNIV GENEVA, DEPT CHIM PHYS, CH-1211 GENEVA, SWITZERLAND
关键词
D O I
10.1088/0957-0233/8/5/003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A helium gas pressure cell for pressures up to 1 kbar (0.1 GPa) has been developed in conjunction with a closed-cycle He refrigerator allowing variable temperatures between 15 and 300 K. Both cell and refrigerator are equipped with optical windows suitable for photophysical measurements, such as temperature- and pressure-dependent absorption spectroscopy or laser flash photolysis. Examples of measurements on iron(II) spin-crossover systems are given. In these compounds, comparatively small external pressures induce significant changes in the thermodynamic equilibrium as well as in the relaxation dynamics.
引用
收藏
页码:479 / 483
页数:5
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