A self-repairing, supramolecular polymer system: healability as a consequence of donor-acceptor π-π stacking interactions

被引:474
作者
Burattini, Stefano [1 ]
Colquhoun, Howard M. [1 ]
Fox, Justin D. [2 ]
Friedmann, Donia [3 ]
Greenland, Barnaby W. [1 ]
Harris, Peter J. F. [1 ]
Hayes, Wayne [1 ]
Mackay, Michael E. [3 ]
Rowan, Stuart J. [2 ]
机构
[1] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England
[2] Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
[3] Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA
基金
英国工程与自然科学研究理事会;
关键词
SEQUENCE INFORMATION; RECOGNITION; MOLECULES; FOLD;
D O I
10.1039/b910648k
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A novel supramolecular polymer system, in which the terminal pyrenyl groups of a polyamide intercalate into the chain-folds of a polyimide via electronically-complementary pi-pi stacking, shows both enhanced mechanical properties relative to those of its individual components and facile healing characteristics as a result of the thermoreversibility of non-covalent interactions.
引用
收藏
页码:6717 / 6719
页数:3
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