Hierarchical Self-Assembly of a Chiral Metal-Organic Framework Displaying Pronounced Porosity

被引：86

作者：

Clegg, Jack K. ^{[1
]}

Iremonger, Simon S. ^{[1
]}

Hayter, Michael J. ^{[1
]}

Southon, Peter D. ^{[1
]}

Macquart, Rene B. ^{[1
]}

Duriska, Martin B. ^{[3
]}

Jensen, Paul ^{[1
]}

Turner, Peter ^{[1
]}

Jolliffe, Katrina A. ^{[1
]}

Kepert, Cameron J. ^{[1
]}

Meehan, George V. ^{[2
]}

Lindoy, Leonard F. ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] James Cook Univ, Sch Pharm & Mol Sci, Townsville, Qld 4814, Australia

[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 06期

基金：

美国国家科学基金会;

关键词：

adsorption; coordination modes; self-assembly; supramolecular chemistry; COPPER(II); METALLOCYCLES; DINUCLEAR; HYDROGEN; SOLVENT; ADSORPTION; IRON(III); DISCRETE; STORAGE; LIGAND;

D O I：

10.1002/anie.200905497

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Into the void: A large, cavity-containing trinuclear triangle with accessible binding sites has been synthesized, structurally characterized, and incorporated into a chiral metal-organic framework (see picture). The resulting 3D framework, with a afunctional amine bridging group, has a void volume of 56% that is accessible to solvent and adsorbs a variety of gases to various degrees. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1075 / 1078

页数：4

共 37 条

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