Singularities in the rheology of saturated humid air, and molecular diffusion in cloods

Under realistic assumptions, we propose a thermodynamical formalism providing, for the moist-saturated air (cloudy air), a generalized Fick's law. This Fick's law leads to a double diffusive rheology with Dufour effect. The form taken by the energy equation is slightly different from the classical form used in convection problems. We compare the equations with those of the convection in moist unsaturated air (the Dufour effect and all double diffusive effects disappear in this case). As application we demonstrate some consequences of this diffusion in cloudy convection.