Towards a synthetic model of the photosynthetic water oxidizing complex:: [Mn3O4(O2CMe)4(bpy)2] containing the [MnIV3(μ-O)4]4+ core

被引:37
作者
Bhaduri, S [1 ]
Pink, M [1 ]
Christou, G [1 ]
机构
[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
关键词
D O I
10.1039/b206302f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 3 Mn-IV title compound has been prepared and characterized by X-ray crystallography and magnetochemistry; the complex contains a [Mn(mu-O)(2)Mn(mu-O)(2)Mn](4+) core and possesses an S = 3/2 ground state.
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页码:2352 / 2353
页数:2
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