Virial approach to hard-sphere demixing

被引：36

作者：

Coussaert, T

Baus, M

机构：

[1] Faculté des Sciences, Université Libre de Bruxelles, Bruxelles, B-1050, Case Postale 231, Campus Plaine

来源：

PHYSICAL REVIEW LETTERS | 1997年 / 79卷 / 10期

关键词：

D O I：

10.1103/PhysRevLett.79.1881

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We propose a perturbative modification of the Carnahan-Starling equation of state for a binary hard-sphere mixture which brings its virial coefficients into better agreement with recent numerical findings. The resulting analytic equation of state predicts a demixing transition whose spinodals and binodals are in qualitative agreement with recent numerical and experimental findings.

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收藏

页码：1881 / 1884

页数：4

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