Combination of neural network and SBFM algorithm for monitoring VOCs distribution by open path FTIR spectrometry

被引:10
作者
Ren, Yibo
Li, Yan [1 ]
Yu, Baihua
Wang, Junde
Hu, LanPing
机构
[1] Nanjing Univ Sci & Technol, Lab Adv Spect, Nanjing 210014, Peoples R China
[2] Nantong Univ, Sch Chem & Chem Engn, Analyt Chem Lab, Nantong, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
atmospheric monitoring; open path FTIR spectrometry; spectra analysis; distribution reconstruction; BP-ANN; SBFM algorithm;
D O I
10.1080/10739140601000400
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this research, the combination of artificial neural network (ANN) modeling and smooth basis function minimization (SBFM) algorithm were applied to Open Path Fourier transform infrared spectroscopy (OP-FTIR) for monitoring volatile organic compounds' concentration distribution in the air. ANN was utilized to analyze the measured mixture spectra containing chloroform, methanol, and methylene chloride; Then, SBFM was used to reconstruct each component's concentration distribution. The peak concentration locations and maximum concentration for three components are reconstructed accurately. The methodology presented in this paper has significant importance in detecting leaking source spot and monitoring airborne VOCs transport in chemical industrial workplaces.
引用
收藏
页码:1 / 14
页数:14
相关论文
共 24 条
  • [1] Quantitative predictive models for octanol-air partition coefficients of polybrominated diphenyl ethers at different temperatures
    Chen, JW
    Harner, T
    Yang, P
    Quan, X
    Chen, S
    Schramm, KW
    Kettrup, A
    [J]. CHEMOSPHERE, 2003, 51 (07) : 577 - 584
  • [2] Novel approach for tomographic reconstruction of gas concentration distributions in air: Use of smooth basis functions and simulated annealing
    Drescher, AC
    Gadgil, AJ
    Price, PN
    Nazaroff, WW
    [J]. ATMOSPHERIC ENVIRONMENT, 1996, 30 (06) : 929 - 940
  • [3] Stationary and time-dependent indoor tracer-gas concentration profiles measured by OP-FTIR remote sensing and SBFM-computed tomography
    Drescher, AC
    Park, DY
    Yost, MG
    Gadgil, AJ
    Levine, SP
    Nazaroff, WW
    [J]. ATMOSPHERIC ENVIRONMENT, 1997, 31 (05) : 727 - 740
  • [4] ESCUDERGILBERT L, 2006, J CHROMATOGR A, V1029, P135
  • [5] New augmented classical least squares methods for improved quantitative spectral analyses
    Haaland, DM
    Melgaard, DK
    [J]. VIBRATIONAL SPECTROSCOPY, 2002, 29 (1-2) : 171 - 175
  • [6] HASHMONAY RA, 1998, SPIE, V3534, P126
  • [7] Huang ZH, 2002, SPECTROSC SPECT ANAL, V22, P973
  • [8] Mapping air contaminant concentrations using remote sensing FTIR
    Li, Y
    Wang, JD
    Huang, ZH
    Zhou, XT
    [J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2003, 38 (02): : 429 - 438
  • [9] Artificial neural network for the quantitative analysis of air toxic VOCs
    Li, Y
    Wang, J
    Chen, ZR
    Zhou, XT
    [J]. ANALYTICAL LETTERS, 2001, 34 (12) : 2203 - 2219
  • [10] Application of evolutionary neural network method in predicting pollutant levels in downtown area of Hong Kong
    Lu, WZ
    Fan, HY
    Lo, SM
    [J]. NEUROCOMPUTING, 2003, 51 : 387 - 400