Palladium catalysis in water: Design, preparation, and use of amphiphilic resin-supported palladium-phosphine complexes

被引：11

作者：

Uozumi, Y ^{[1
]}

机构：

[1] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2002年 / 60卷 / 11期

关键词：

D O I：

10.5059/yukigoseikyokaishi.60.1063

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed synthetic transformations (pi-allylic substitution, carbonylation, cross-coupling, etc.) were achieved in water by use of amphiphilic polystyrene-poly(ethylene glycol) resin (PS-PEG)-supported palladium-phosphine complexes. Asymmetric allylic alkylation of cyclic allyl esters was catalyzed by a palladium complex of a PS-PEG-supported chiral (imidazoindole)phosphine ligand with high enantioselectivity of up to 99% ee.

引用

页码：1063 / 1068

页数：6

共 49 条

[1] Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions [J].