L-cysteine functionalized gold nanoparticles for the colorimetric detection of Hg2+ induced by ultraviolet light

被引:174
作者
Chai, Fang [1 ,2 ]
Wang, Chungang [1 ]
Wang, Tingting [1 ]
Ma, Zhanfang [3 ]
Su, Zhongmin [1 ]
机构
[1] NE Normal Univ, Fac Chem, Inst Funct Mat Chem, Changchun 130024, Peoples R China
[2] Harbin Normal Univ, Dept Chem, Harbin 150500, Peoples R China
[3] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-IONS; MERCURY(II) IONS; SENSITIVE DETECTION; BIOSENSORS; DNAZYME; DESIGN; SERS;
D O I
10.1088/0957-4484/21/2/025501
中图分类号
TB3 [工程材料学];
学科分类号
082905 [生物质能源与材料];
摘要
A simple, cost-effective yet rapid and sensitive colorimetric sensor for the detection of Hg2+ using L-cysteine functionalized gold nanoparticles induced by ultraviolet radiation was developed. The sensitivity and selectivity of detection was also investigated. The L-cysteine modified gold nanoparticles can be induced to aggregate quickly in the presence of Hg2+, especially with the assistance of ultraviolet radiation. The presence of Hg2+ can be monitored by the colorimetric response of gold nanoparticles. The detection of Hg2+ could be realized, after measuring the UV-vis spectra, with a detection limit of 100 nM. The selectivity of this method has been investigated by other divalent metal ions. The effective colorimetric sensor can be used for on-site and real-time Hg2+ detection.
引用
收藏
页数:6
相关论文
共 31 条
[1]
A review of mercury in Lake Victoria, East Africa: Implications for human and ecosystem health [J].
Campbell, LM ;
Dixon, DG ;
Hecky, RE .
JOURNAL OF TOXICOLOGY AND ENVIRONMENTAL HEALTH-PART B-CRITICAL REVIEWS, 2003, 6 (04) :325-356
[2]
A general strategy to convert the MerR family proteins into highly sensitive and selective fluorescent biosensors for metal ions [J].
Chen, P ;
He, CA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (03) :728-729
[3]
Selective detection of mercury (II) ion using nonlinear optical properties of gold nanoparticles [J].
Darbha, Gopala Krishna ;
Singh, Anant Kumar ;
Rai, Uma Shanker ;
Yu, Eugene ;
Yu, Hongtao ;
Ray, Paresh Chandra .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) :8038-8043
[4]
Design of a gold nanoprobe for rapid and portable mercury detection with the naked eye [J].
He, Shijiang ;
Li, Di ;
Zhu, Changfeng ;
Song, Shiping ;
Wang, Lihua ;
Long, Yitao ;
Fan, Chunhai .
CHEMICAL COMMUNICATIONS, 2008, (40) :4885-4887
[5]
Dose-dependent inorganic mercury absorption by isolated perfused intestine of rainbow trout, Oncorhynchus mykiss, involves both amiloride-sensitive and energy-dependent pathways [J].
Hoyle, I ;
Handy, RD .
AQUATIC TOXICOLOGY, 2005, 72 (1-2) :147-159
[6]
Gold nanoparticle-based sensing of "spectroscopically silent" heavy metal ions [J].
Kim, YJ ;
Johnson, RC ;
Hupp, JT .
NANO LETTERS, 2001, 1 (04) :165-167
[7]
Colorimetric detection of mercuric ion (Hg2+) in aqueous media using DNA-functionalized gold nanoparticles [J].
Lee, Jae-Seung ;
Han, Min Su ;
Mirkin, Chad A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (22) :4093-4096
[8]
ADSORPTION AND SURFACE-ENHANCED RAMAN OF DYES ON SILVER AND GOLD SOLS [J].
LEE, PC ;
MEISEL, D .
JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (17) :3391-3395
[9]
Elimination efficiency of different reagents for the memory effect of mercury using ICP-MS [J].
Li, YF ;
Chen, CY ;
Li, B ;
Sun, J ;
Wang, JX ;
Gao, YX ;
Zhao, YL ;
Chai, ZF .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2006, 21 (01) :94-96
[10]
Detection of mercury(II) based on Hg2+-DNA complexes inducing the aggregation of gold nanoparticles [J].
Liu, Chi-Wei ;
Hsieh, Yi-Ting ;
Huang, Chih-Ching ;
Lin, Zong-Hong ;
Chang, Huan-Tsung .
CHEMICAL COMMUNICATIONS, 2008, (19) :2242-2244