Enantioselective reduction of aromatic ketones catalysed by chiral ruthenium(II) complexes

被引：35

作者：

Aitali, M

Allaoud, S

Karim, A

Meliet, C

Mortreux, A

机构：

[1] Univ Cadi Ayyad, Fac Sci Semlalia, Dept Chim, Marrakech, Morocco

[2] ENSCL, UPRESA CNRS 8010, Lab Catalyse Lille, Grp Chim Organ Appl, F-59652 Villeneuve Dascq, France

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(00)00055-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic enantioselective reduction of aromatic ketones in 2-propanol is carried out by using ruthenium(II) complexes prepared from [Ru(p-cymene)Cl-2](2) and a variety of chiral diamines and p-aminoalcohols derived from alpha-amino acids. Good conversions (>99%) and enantioselectivities (=96%) are observed under mild reaction conditions. (C) 2000 Elsevier Science Ltd. All rights reserved.

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页码：1367 / 1374

页数：8

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