The radical rate-determining step in the oxidation of benzyl alcohols by two N-OH-type mediators of laccase:: the polar N-oxyl radical intermediate

被引：45

作者：

d'Acunzo, F

Baiocco, P

Fabbrini, M

Galli, C ^{[1
]}

Gentili, P

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

[2] Univ Roma La Sapienza, Ctr CNR Meccanismi Reaz, I-00185 Rome, Italy

来源：

NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 12期

关键词：

D O I：

10.1039/b206928h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Determination of the effect of substituents in the aerobic oxidation of X-substituted benzyl alcohols by laccase, with mediation by HPI or HBT, confirms the H-atom abstraction from the benzylic C H bond as the rate-determining step ( HAT route), and supports a polar nature for the N-oxyl radical intermediate originating from the two N-OH mediators.

引用

页码：1791 / 1794

页数：4

共 36 条

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