Asymmetric synthesis of (S)-1-methyl-2-cyclohexen-1-ol, a constituent of the aggregation pheromone of Dendroctonus pseudotsugae

被引：9

作者：

Hamon, DPG ^{[1
]}

Tuck, KL ^{[1
]}

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

来源：

TETRAHEDRON | 2000年 / 56卷 / 27期

关键词：

asymmetric synthesis; hydroxylation; elimination reactions; pheromones;

D O I：

10.1016/S0040-4020(00)00402-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-Methyl-2-cyclohexen-1-ol has been prepared by a three step synthesis from 1-methylcyclohexene, in greater than 94% e.e., via a 'merged substitution-elimination reaction' between NaSePh and 2-methyl-2-hydroxycyclohexyl p-toluenesulphonate. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4829 / 4835

页数：7

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