Use of Reflectance Infrared Spectroscopy for Monitoring the Metal Content of the Estuarine Sediments of the Nerbioi-Ibaizabal River (Metropolitan Bilbao, Bay of Biscay, Basque Country)

被引：90

作者：

Moros, Javier ^{[1
]}

Fdez-Ortiz de Vallejuelo, Silvia ^{[2
]}

Gredilla, Ainara ^{[2
]}

de Diego, Alberto ^{[2
]}

Manuel Madariaga, Juan ^{[2
]}

Garrigues, Salvador ^{[1
]}

de la Guardia, Miguel ^{[1
]}

机构：

[1] Univ Valencia, Dept Analyt Chem, E-46100 Valencia, Spain

[2] Univ Basque Country, Dept Analyt Chem, Bilbao 48080, Basque Country, Spain

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2009年 / 43卷 / 24期

关键词：

PARTIAL LEAST-SQUARES; ORGANIC-MATTER; HEAVY-METALS; REGION; SOILS; CHEMOMETRICS; SPECTROMETRY; EXAMPLE; DEEP;

D O I：

10.1021/es9005898

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Multivariate partial least-squares (PLS) calibration models have been developed for the spatial and seasonal simultaneous monitoring of 14 trace elements (AI, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sn, V, and Zn) in sediments from 117 samples taken in the estuary of the Nerbioi-Ibaizabal River. Models were based on the chemometric treatment of diffuse reflectance near-infrared (NIR) and attenuated total reflectance (ATR) mid infrared (MIR) spectra, obtained from samples previously lyophilized and sieved with a particle size lower than 63 mu m. Vibrational spectra were scanned in both, NIR and MIR regions. Developed PLS models, based on the interaction between trace elements and organic mater provide good screening tools for the prediction of trace elements concentration in sediments.

引用

页码：9314 / 9320

页数：7

共 34 条

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