Structure of azo dye organotin(IV) compounds containing a C,N-chelating ligand

被引:36
作者
Ruzicka, A
Lycka, A
Jambor, R
Novák, P
Císarová, L
Holcapek, M
Erben, M
Holecek, J
机构
[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, CZ-53210 Pardubice, Czech Republic
[2] Res Inst Organ Synth, CZ-53218 Pardubice, Czech Republic
[3] Charles Univ Prague, Fac Nat Sci, Prague 12840 2, Czech Republic
[4] Univ Pardubice, Fac Chem Technol, Dept Analyt Chem, CZ-53210 Pardubice, Czech Republic
关键词
organotin(IV) compounds; azo dyes; C; N-ligand; NMR; X-ray diffraction; electrospray ionization mass spectrometry;
D O I
10.1002/aoc.401
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Two complexes derived from simple azo dyes (methyl orange and para-methyl red) and the [(2-dimethylaminomethyl)phenyl](diphenyl)tin(IV) moiety have been prepared and their NMR, MS, IR, Raman and UV-VIS spectra were measured and X-ray structures determined. Both compounds reveal the same structure in chloroform and in the solid state. The central tin atoms exist in a slightly distorted trans-trigonal bipyramidal geometry. Copyright (C) 2003 John Wiley Sons, Ltd.
引用
收藏
页码:168 / 174
页数:7
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