Novel modified soybean oil containing hydrazino-ester: synthesis and characterization

被引：30

作者：

Biswas, Atanu

Sharma, Brajendra K.

Willet, J. L.

Vermillion, K.

Erhan, Sevim Z.

Cheng, H. N.

机构：

[1] USDA ARS, Natl Ctr Agr Utilizat Res, Plant Polymer Res Unit, Peoria, IL 61604 USA

[2] USDA ARS, Natl Ctr Agr Utilizat Res, Food & Ind Oil Res Unit, Peoria, IL 61604 USA

[3] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA

[4] USDA ARS, Natl Ctr Agr Utilizat Res, New Crops & Proc Technol Res Unit, Peoria, IL 61604 USA

[5] Hercules Inc Res Ctr, Wilmington, DE 19808 USA

来源：

GREEN CHEMISTRY | 2007年 / 9卷 / 01期

关键词：

D O I：

10.1039/b608075h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel synthetic approach for chemical modification of vegetable oils is presented. The structural modification is carried out using diethyl azodicarboxylate (DEAD) in the absence of catalyst and solvent. In a microwave oven the reaction can be achieved in 5-15 minutes. The reaction can also proceed using conventional heat, albeit for a longer time. The products are characterized by H-1, C-13, and two-dimensional NMR.

引用

页码：85 / 89

页数：5

共 33 条

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