A 9-borylated acridinyl radical

被引：101

作者：

Chiu, Ching-Wen ^{[1
]}

Gabbai, Francois P. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 10期

关键词：

boron; carbocations; multiple bonds; radicals; reduction;

D O I：

10.1002/anie.200604119

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An odd molecule with an unpaired electron: Reduction of a cationic borane bearing an α-methylium center leads to the formation of a neutral radical, which has been studied by X-ray analysis and EPR spectroscopy. The computed spin density (see picture, right) of this radical shows substantial localization of the unpaired electron in a polarized B-C π-bonding orbital, a conclusion corroborated by an unusually short B-C bond. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1723 / 1725

页数：3

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