Modulating rheological properties of supramolecular networks by pH-responsive double-axle intrusion into γ-cyclodextrin

被引：35

作者：

Joung, Yoon-Ki ^{[1
]}

Ooya, Tooru ^{[1
]}

Yamaguchi, Masayuki ^{[1
]}

Yui, Nobuhiko ^{[1
]}

机构：

[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan

来源：

ADVANCED MATERIALS | 2007年 / 19卷 / 03期

关键词：

D O I：

10.1002/adma.200600604

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A pH-responsive supramolecular network formed from gamma-cyclodextrin and linear poly(ethylene glycol)-blockpoly(ethyleneimine) (PEG-b-PEI) copolymers (see figure) by double-axle intrusion (DI) can modulate its rheological properties in response to pH changes. The formation of the DI system induces a drastic increase in the rheological properties even under very diluted conditions. The DI system shows significantly reduced viscoelastic properties at low pH.

引用

页码：396 / +

页数：6

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