interaction potential;
collision integrals;
direct inversion method;
extended principle of corresponding states;
D O I:
10.1016/S0378-3812(02)00191-7
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
Viscosity, diffusion coefficients, and thermal diffusion factors for five equimolar binary gas mixtures of CO-noble gases are determined from the principle of corresponding states of viscosity by the inversion technique. The Lennard-Jones 12-6 (LJ 12-6) potential energy function is used as the initial model potential required by the technique. The interaction potential energies from the inversion procedure reproduce viscosity within 1%, diffusion coefficients within 5%, and thermal diffusion factors within 25%. (C) 2002 Elsevier Science B.V. All rights reserved.