Calculation of the transport properties of CO-noble gases mixtures at low density by the semi-empirical inversion method

被引:31
作者
Haghighi, B
Fathabadi, M
Papari, MM
机构
[1] Univ Birjand, Dept Chem, Birjand, Iran
[2] Shiraz Univ, Dept Chem, Shiraz, Iran
关键词
interaction potential; collision integrals; direct inversion method; extended principle of corresponding states;
D O I
10.1016/S0378-3812(02)00191-7
中图分类号
O414.1 [热力学];
学科分类号
摘要
Viscosity, diffusion coefficients, and thermal diffusion factors for five equimolar binary gas mixtures of CO-noble gases are determined from the principle of corresponding states of viscosity by the inversion technique. The Lennard-Jones 12-6 (LJ 12-6) potential energy function is used as the initial model potential required by the technique. The interaction potential energies from the inversion procedure reproduce viscosity within 1%, diffusion coefficients within 5%, and thermal diffusion factors within 25%. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:205 / 225
页数:21
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