Hydrocarbonylation of prop-2-en-1-ol catalysed by zeolite-encapsulated rhodium species: Chemoselectivity effects imposed by the zeolite support

被引：16

作者：

Currie, AWS ^{[1
]}

Andersen, JAM ^{[1
]}

机构：

[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

CATALYSIS LETTERS | 1997年 / 44卷 / 1-2期

关键词：

zeolites; encapsulated; rhodium; hydrocarbonylation;

D O I：

10.1023/A:1018960621837

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zeolite-encapsulated catalysts, [Rh(CO)(x)(PR3)(y)]-zeolite, exhibit markedly different chemoselectivities to their homogeneous counterparts; furans and pyrans are formed from the hydrocarbonylation of prop-2-en-1-ol or but-3-en-1-ol instead of the expected diols. The nature of the zeolite support was found to influence the selectivity of the reaction.

引用

页码：109 / 111

页数：3

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