A novel dicationic phenoxaphosphino-modified Xantphos-type ligand - a unique ligand specifically designed for a high activity, selectivity and recyclability

被引：79

作者：

Bronger, RPJ

Silva, SM

Kamer, PCJ

van Leeuwen, PWNM

机构：

[1] Univ Amsterdam, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands

[2] Univ Fed Rio Grande do Sul, Lab Mol Catalysis, Inst Quim, BR-91501970 Porto Alegre, RS, Brazil

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 24期

关键词：

D O I：

10.1039/b209486j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel phenoxaphosphino-modified ligand has been prepared and successfully employed in the rhodium catalysed hydroformylation of 1-octene in ionic liquids showing unprecedented high selectivity and activity without detectable rhodium or phosphorus leaching during recycling experiments.

引用

收藏

页码：3044 / 3045

页数：2

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