Sol-gel entrapped TEMPO for the selective oxidation of methyl α-D-glucopyranoside

被引：86

作者：

Ciriminna, R

Blum, J

Avnir, D

Pagliaro, M ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel

[2] CNR, Inst Chem & Technol Nat Prod, I-90146 Palermo, Italy

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b003096l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sol-gel entrapment of TEMPO within a silica matrix yields an efficient and recyclable catalytic system for the selective oxidation of methyl alpha-d-glucopyranoside (MGP) in water with NaOCl as primary oxidant, thus opening the way to the heterogeneous catalysis of the conversion of sugars into valuable uronates.

引用

页码：1441 / 1442

页数：2

共 18 条

[1] ORGANIC-CHEMISTRY WITHIN CERAMIC MATRICES - DOPED SOL-GEL MATERIALS
AVNIR, D
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (08) : 328 - 334
[2] Blum J, 1999, CHEMTECH, V29, P32
[3] NEW METHOD FOR QUANTITATIVE-DETERMINATION OF URONIC ACIDS
BLUMENKR.N
ASBOEHAN.G
[J]. ANALYTICAL BIOCHEMISTRY, 1973, 54 (02) : 484 - 489
[4] DETOXIFICATION OR CHEMICAL DEFENSE BY GLUCURONIDATION - AN UNDERGRADUATE BIOCHEMISTRY EXPERIMENT
BOIRET, M
MARTY, A
[J]. JOURNAL OF CHEMICAL EDUCATION, 1986, 63 (11) : 1009 - 1011
[5] TEMPO oxidations with a silica-supported catalyst
Bolm, C
Fey, T
[J]. CHEMICAL COMMUNICATIONS, 1999, (18) : 1795 - 1796
[6] deNooy AEJ, 1996, SYNTHESIS-STUTTGART, P1153
[7] SELECTIVE OXIDATION OF PRIMARY ALCOHOLS MEDIATED BY NITROXYL RADICAL IN AQUEOUS-SOLUTION - KINETICS AND MECHANISM
DENOOY, AEJ
BESEMER, AC
VANBEKKUM, H
[J]. TETRAHEDRON, 1995, 51 (29) : 8023 - 8032
[8] Synthesis of alpha- and beta-D-glucopyranuronate 1-phosphate and alpha-D-glucopyranuronate 1-fluoride: Intermediates in the synthesis of D-glucuronic acid from starch
Heeres, A
vanDoren, HA
Gotlieb, KF
Bleeker, IP
[J]. CARBOHYDRATE RESEARCH, 1997, 299 (04) : 221 - 227
[9] HEERES A, 1996, Patent No. 36621
[10] KUNZ M, 1995, CARBOHYDR EUROPE, V13, P11

← 1 2 →