Novel examples of cluster-matter produced by LUCAS, a new laser cluster source

被引:10
作者
Gartz, M [1 ]
Keutgen, C [1 ]
Kuenneke, S [1 ]
Kreibig, U [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Phys 1, D-52056 Aachen, Germany
关键词
D O I
10.1007/s100530050411
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present experimental results obtained by a novel cluster source, LUCAS, based on laser ablation/evaporation of high cluster yield. Deposition rates of approximate to 10 nm/s can be achieved for a broad held of materials. Experiments on three different examples of cluster-matter are presented. (1) Iron clusters (2R = 20 nm) are embedded in fullerite and compared to sliver clusters (2R = 2.6 nm) where previously static and dynamic charge transfer has been detected [1]. (2) The chemical reactions of Y clusters (2R = 16 nm) with hydrogen and oxygen exhibit reversible and non-reversible structural and electronic phase transitions. (3) Crystalline ITO clusters are produced in nanoporous optical films (thickness 190 nm) with high conductivity and good stability.
引用
收藏
页码:127 / 131
页数:5
相关论文
共 11 条
[1]  
HUIBERTS JN, 1996, LETT NAT, V380
[2]  
KLEINWIEHLE J, 1998, UNPUB PHYS REV LETT
[3]   Mie resonances: Sensors for physical and chemical cluster interface properties [J].
Kreibig, U ;
Gartz, M ;
Hilger, A .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1997, 101 (11) :1593-1604
[4]  
Kreibig U., 1995, OPTICAL PROPERTIES M
[5]   Femtosecond decay-time measurement of electron-plasma oscillation in nanolithographically designed silver particles [J].
Lamprecht, B ;
Leitner, A ;
Aussenegg, FR .
APPLIED PHYSICS B-LASERS AND OPTICS, 1997, 64 (02) :269-272
[6]  
MAASS J, 1996, THESIS U TECHNOLOGY
[7]   POLARIZABILITY OF SMALL SPHERICAL METAL PARTICLES - INFLUENCE OF THE MATRIX ENVIRONMENT [J].
PERSSON, BNJ .
SURFACE SCIENCE, 1993, 281 (1-2) :153-162
[8]   Lorenz-Mie theory for spheres immersed in an absorbing host medium [J].
Quinten, M ;
Rostalski, J .
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, 1996, 13 (02) :89-96
[9]   Optical switches based on magnesium lanthanide alloy hydrides [J].
vanderSluis, P ;
Ouwerkerk, M ;
Duine, PA .
APPLIED PHYSICS LETTERS, 1997, 70 (25) :3356-3358
[10]   ELECTRONIC-STRUCTURE OF METAL-HYDRIDES .1. OPTICAL STUDIES OF SCH2, YH2, AND LUH2 [J].
WEAVER, JH ;
ROSEI, R ;
PETERSON, DT .
PHYSICAL REVIEW B, 1979, 19 (10) :4855-4866