Preparation of NHC-ruthenium complexes and their catalytic activity in metathesis reaction

被引：199

作者：

Colacino, Evelina

Martinez, Jean

Lamaty, Frederic ^{[1
]}

机构：

[1] Univ Montpellier I, LAPP, CNRS, Pl Eugene Bataillon, F-34095 Montpellier 5, France

[2] Univ Montpellier 2, LAPP, CNRS, F-34095 Montpellier 5, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2007年 / 251卷 / 5-6期

关键词：

N-heterocyclic carbenes; homogeneous ruthenium catalysts; supported ruthenium catalysts; RCM mechanism;

D O I：

10.1016/j.ccr.2006.07.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A detailed overview on the synthesis of four-, five- and six-membered, saturated and unsaturated N-heterocyclic carbenes used in the preparation of their corresponding ruthenium complexes (Grubbs' second-generation, Fischer-type, Hoveyda-Grubbs, homo and hetero-bimetallic) is presented both in solution and on solid support. The catalytic activity of the different complexes in ruthenium-catalyzed metathesis reaction is compared and explained by their structural features. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：726 / 764

页数：39

共 184 条

[1] Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM [J].