Color centers in lead molybdate crystals

被引:43
作者
Bochkova, TM [1 ]
Volnyanskii, MD [1 ]
Volnyanskii, DM [1 ]
Shchetinkin, VS [1 ]
机构
[1] Dnepropetrovsk Natl Univ, UA-49050 Dnepropetrovsk, Ukraine
关键词
D O I
10.1134/1.1553525
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 [凝聚态物理];
摘要
Color center formation in PbMoO4 crystals, originating from nonstoichiometric batch composition, BaO and Bi2O3 additions, high-temperature annealing of crystals, and UV illumination, is discussed. Additional optical absorption bands are identified. The photochromism of the crystals is shown to be due to charge exchange, Pb2+ + Mo(6+)reversible arrow Pb3+ + Mo5+, of the centers. (C) 2003 MAIK "Nauka / Interperiodica".
引用
收藏
页码:244 / 247
页数:4
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